WITHDRAWN: Polyoxometalate-catalyzed hydrolysis of the hemicelluloses by (Mo-V-P)-heteropolyacids - Statistical modeling using response surfaces.
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DOI: 10.1016/j.carbpol.2019.115799
Abstract: Abstract The mixed-addenda Keggin-type molybdovanadophosphate heteropolyacids (Mo-V-P)-HPAs of series H(n+3)[PMo(12-n)VnO40] with n = 3,4 (HPA-3 and HPA-4) were found to be extremely effective acid catalysts for green hydrolytic conversion of plant (wood and agro-crop) hemicelluloses into soluble… read more here.
Keywords: withdrawn polyoxometalate; polyoxometalate catalyzed; response; hpa ... See more keywords
Polyoxometalate catalyzed imine synthesis: Investigation of mechanistic pathways
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DOI: 10.1016/j.tet.2020.131245
Abstract: Abstract The syntheses of imines by oxidative coupling of primary alcohols and amines were achieved by using 2 mol% polyoxometalate (POM) Na12[WZn3(H2O)2(ZnW9O34)2] (Zn–WZn3) catalyst in the presence of t-BuOK and di-oxygen with excellent conversion (up to… read more here.
Keywords: polyoxometalate catalyzed; investigation mechanistic; synthesis investigation; imine synthesis ... See more keywords