Computational Insights into Iron Heterometal Installation in Polyoxovanadate-Alkoxide Clusters.
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DOI: 10.1021/acs.inorgchem.1c03589
Abstract: Polyoxovanadate-alkoxide clusters are a new class of electroactive species with applications in a wide variety of fields from redox catalysis to energy storage. Heterometallic installation in these species can be used to modulate the redox… read more here.
Keywords: polyoxovanadate; installation; alkoxide clusters; polyoxovanadate alkoxide ... See more keywords
Hybrid Molecular Magnets with Lanthanide- and Countercation-Mediated Interfacial Electron Transfer between Phthalocyanine and Polyoxovanadate.
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DOI: 10.1021/acs.inorgchem.2c03599
Abstract: A series of {V12}-nuclearity polyoxovanadate cages covalently functionalized with one or sandwiched by two phthalocyaninato (Pc) lanthanide (Ln) moieties via V-O-Ln bonds were prepared and fully characterized for paramagnetic Ln = SmIII-ErIII and diamagnetic Ln… read more here.
Keywords: electron transfer; nbu4n hv12o32cl; polyoxovanadate; transfer ... See more keywords