Charge-State Dependence of Proton Uptake in Polyoxovanadate-alkoxide Clusters
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c02937
Abstract: Here, we present an investigation of the thermochemistry of proton uptake in acetonitrile across three charge states of a polyoxovanadate-alkoxide (POV-alkoxide) cluster, [V6O7(OMe)12]n (n = 2–, 1–, and 0). The vanadium oxide assembly studied features… read more here.
Keywords: polyoxovanadate alkoxide; charge; proton uptake; cluster ... See more keywords
Computational Insights into Iron Heterometal Installation in Polyoxovanadate-Alkoxide Clusters.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03589
Abstract: Polyoxovanadate-alkoxide clusters are a new class of electroactive species with applications in a wide variety of fields from redox catalysis to energy storage. Heterometallic installation in these species can be used to modulate the redox… read more here.
Keywords: polyoxovanadate; installation; alkoxide clusters; polyoxovanadate alkoxide ... See more keywords
Molecular Engineering of Polyoxovanadate-Alkoxide Clusters and Microporous Polymer Membranes to Prevent Crossover in Redox-Flow Batteries
Sign Up to like & getrecommendations! Published in 2022 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.1c23205
Abstract: The ongoing development of redox-active charge carriers for nonaqueous redox-flow batteries has led to energy-dense storage concepts and chemistries with high cell voltages. However, rarely are these candidates for flowable energy storage evaluated in tandem… read more here.
Keywords: redox flow; alkoxide clusters; polyoxovanadate alkoxide; redox ... See more keywords