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Published in 2018 at "Advanced Energy Materials"
DOI: 10.1002/aenm.201702897
Abstract: DOI: 10.1002/aenm.201702897 easy to scale in principle.[1] When operated in a flow-through mode, soluble redox couples dissolved in liquid media and stored in large reservoirs can be supplied to the electrochemical cell on demand.[2] Unfortunately,…
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Keywords:
energy;
flow batteries;
redox;
cobalt polypyridyl ... See more keywords
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Published in 2017 at "Journal of Fluorescence"
DOI: 10.1007/s10895-017-2029-y
Abstract: Three ruthenium(II) polypyridyl complexes, [Ru(phen)2(mip)](ClO4)2 (1) (phen =1,10-Phenanthroline), [Ru(bpy)2(mip)](ClO4)2 (2) (bpy = 2,2’bipyridyl) and [Ru(dmb)2(mip)](ClO4)2 (3) (dmb = 4, 4′-dimethyl 2, 2′-bipyridine), were synthesized with an intercalative ligand mip (2-morpholino-1H-imidazo[4,5-f][1, 10]phenanthroline) and characterized by 1H, 13C–NMR, IR, UV-vis, mass…
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Keywords:
mip clo4;
dna;
bsa;
sensitivity ... See more keywords
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Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118964
Abstract: Abstract A series of complexes of the type [Pt(PL)(AL)(X)2]2+ (where PL = 1,10-phenanthroline, 5-methyl-1,10-phenanthroline or 5,6-dimethyl-1,10-phenanthroline; AL = 1S,2S-diaminocyclohexane and, X = Cl, Br or I) with anticancer potency, were synthesised in a one pot reaction using N-halogensuccinimide (NXS) as both…
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Keywords:
polypyridyl complexes;
synthesis characterisation;
platinum polypyridyl;
axial ligands ... See more keywords
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Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.04.028
Abstract: A new ligand PFPIP (PFPIP=2-(2,3,4,5,6-pentafluorophenyl)[4,5-f]imadazo [1,10]phenanthroline) and its four ruthenium(II) polypyridyl complexes [Ru(NN)2(PFPIP)](ClO4)2 (NN=dmb: 4,4'-dimethyl-2,2'-bipyridine, 1; bpy: 2,2'-bipyridine, 2; phen: 1,10-phenanthroline, 3; dmp: 2,9-dimethyl-1,10-phenanthroline, 4) were synthesized and characterized by elemental analysis, IR, 1H NMR,…
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Keywords:
polypyridyl complexes;
cell;
ruthenium polypyridyl;
bel 7402 ... See more keywords
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Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111301
Abstract: Two chiral Ru(II) polypyridyl complexes, Δ-[Ru(bpy)2(6-F-dppz)]2+ (Δ-1; bpy = 2,2'-bipyridine, 6-F-dppz = 6-fluorodipyrido[3,2-a:2',3'-c]phenazine) and Λ-[Ru(bpy)2(6-F-dppz)]2+ (Λ-1), have been synthesized and characterized as binders for the RNA poly(U)•poly(A)*poly(U) triplex and poly(A)•poly(U) duplex in this work. Analysis of the UV-Vis absorption…
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Keywords:
chiral polypyridyl;
rna;
base paired;
base ... See more keywords
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Published in 2021 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2021.111652
Abstract: In recent years, Ru polypyridyl complexes have been intensively studied for their anticancer activity. The vast majority of research focuses on assessing their cytotoxic activity, as well as targeting cancer cells with them. Since the…
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Keywords:
polypyridyl complexes;
cytotoxic activity;
activity;
metastasis ... See more keywords
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Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01231
Abstract: The synthesis and photophysical characterization of two osmium(II) polypyridyl complexes, [Os(TAP)2dppz]2+ (1) and [Os(TAP)2dppp2]2+ (2) containing dppz (dipyrido[3,2-a:2′,3′-c]phenazine) and dppp2 (pyrido[2′,3′:5,6]pyrazino[2,3-f][1,10]phenanthroline) intercalating ligands and TAP (1,4,5,8-tetraazaphenanthrene) ancillary ligands, are reported. The complexes exhibit complex electrochemistry…
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Keywords:
osmium polypyridyl;
dna;
dna binding;
polypyridyl complexes ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02214
Abstract: Four new ruthenium(II) polypyridyl complexes were synthesized to study the effect of poly(ethylene glycol) and/or biotin conjugation on their physical and biological properties, including their hydrophilicity, their cellular uptake, and their phototoxicity. Unexpectedly, these complexes…
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Keywords:
red absorbing;
biological media;
complexes biotin;
absorbing polypyridyl ... See more keywords
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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01630
Abstract: A series of new Bodipy dyes incorporating the π-extended isoquino[5,6-c]pyrrole have been synthesized and characterized. The dyes display intense Bodipy (π-π*) transitions and emissions with high quantum efficiencies. Spectroscopic, electrochemical, and theoretical calculations are used…
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Keywords:
polypyridyl complexes;
spectroscopic electrochemical;
ruthenium polypyridyl;
bodipy dyes ... See more keywords
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Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00091
Abstract: Two heteronuclear ruthenium(II)-platinum(II) complexes [Ru(bpy)2(BPIMBp)PtCl2]2+ (3) and [Ru(phen)2(BPIMBp)PtCl2]2+ (4), where bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline, and BPIMBp = 1,4'-bis[(2-pyridin-2-yl)-1H-imidazol-1-ylmethyl]-1,1'-biphenyl, have been designed and synthesized from their mononuclear precursors [Ru(bpy)2(BPIMBp)]2+ (1) and [Ru(phen)2(BPIMBp)]2+ (2) as…
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Keywords:
polypyridyl complexes;
bpimbp;
ruthenium platinum;
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Published in 2020 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.9b03562.s001
Abstract: Four novel monocationic Ru(II) polypyridyl complexes were synthesized with the general formula [Ru(DIP)2flv]X, where DIP is 4,7-diphenyl-1,10-phenanthroline, flv stands for the flavonoid ligand (5-hydroxyflavone in [Ru(DIP)2(5-OHF)](PF6), genistein in [Ru(DIP)2(gen)](PF6), chrysin in [Ru(DIP)2(chr)](OTf), and morin in…
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Keywords:
pf6;
activity;
dip;
polypyridyl complexes ... See more keywords