Biomass-derived mesoporous Hf-containing hybrid for efficient Meerwein-Ponndorf-Verley reduction at low temperatures
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.01.017
Abstract: Abstract The use of organic chemicals derived from renewable sources to synthesize functional solid materials for heterogeneous catalysis is of great significance. Herein, a new porous and acid-base bifunctional hybrid (FDCA-Hf) was designed and prepared… read more here.
Keywords: verley reduction; meerwein ponndorf; acid base; biomass derived ... See more keywords
Base-Mediated Meerwein-Ponndorf-Verley Reduction of Aromatic and Heterocyclic Ketones.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02342
Abstract: An experimental protocol to achieve the Meerwein-Ponndorf-Verley (MPV) reduction of ketones under mildly basic conditions is reported. The transformation is tolerant of a range of ketone substrates, including O- and S-containing heterocycles, is scalable, and… read more here.
Keywords: base mediated; reduction; meerwein ponndorf; ponndorf verley ... See more keywords
A Scalable Upgrading of Concentrated Furfural in Ethanol: Combining Meerwein–Ponndorf–Verley Reduction with in Situ Cross Aldol Condensation
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.7b04770
Abstract: Currently, the catalytic upgrade of biomass-derived platform molecules into valuable chemicals is of great interest. In this work, an integrated route for upgrading concentrated furfural (17.3–80.5 wt %) in ethanol through the combination of Meerwein–Ponndorf–Verley… read more here.
Keywords: furfural ethanol; upgrading concentrated; verley reduction; meerwein ponndorf ... See more keywords
Amberlyst-15 supported zirconium sulfonate as an efficient catalyst for Meerwein-Ponndorf-Verley reductions.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00157h
Abstract: The Meerwein-Ponndorf-Verley (MPV) reaction is an important chemoselective route for carbonyl group hydrogenation, and thus designing new and effective catalysts for this transformation remains important and challenging. In this work, a new sulfonate coordinated Zr(IV)… read more here.
Keywords: ponndorf verley; sulfonate; meerwein ponndorf;
Enantioselective Meerwein-Ponndorf-Verley Reduction of β,γ-Unsaturated α-Keto Esters by Asymmetric Binary-Acid Catalysis in Green Solvent iPrOH
Sign Up to like & getrecommendations! Published in 2023 at "Green Chemistry"
DOI: 10.1039/d2gc03441g
Abstract: Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%... read more here.
Keywords: enantioselective meerwein; reduction unsaturated; ponndorf verley; acid ... See more keywords
Continuous flow Meerwein–Ponndorf–Verley reduction of HMF and furfural using basic zirconium carbonate
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra00588c
Abstract: Continuous Flow Microreactors and Green Chemistry are areas with promising applications, especially when allied. In this scenario, the main goal of this study was to develop new strategies for the synthesis of bio-based compounds under… read more here.
Keywords: ponndorf verley; zirconium carbonate; basic zirconium; continuous flow ... See more keywords