Face-selective adsorption of a prochiral compound on the chiral pore-surface of a metal-macrocycle framework (MMF) directed towards stereoselective reactions.
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DOI: 10.1039/d0fd00019a
Abstract: Molecular adsorption on a surface is a unique way to break the mirror-symmetry of prochiral molecules, and therefore the use of chiral surfaces is an effective strategy for achieving highly selective chiral separation and asymmetric… read more here.
Keywords: adsorption; surface; chiral pore; pore surface ... See more keywords