Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00899
Abstract: Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co… read more here.
Keywords: length; coupling porous; antiferromagnetic coupling; control interchain ... See more keywords
A porous Ti-based metal-organic framework for CO2 photoreduction and imidazole-dependent anhydrous proton conduction.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06214c
Abstract: The anhydrous proton conductivity of Im@IEF-11 resulting from the integration of imidazole and porous IEF-11 has been investigated, and the highest proton conductive value can reach up to 7.64 × 10-2 S cm-1. Furthermore, IEF-11… read more here.
Keywords: organic framework; metal organic; anhydrous proton; based metal ... See more keywords