Size-Controlled Synthesis of Luminescent Few-Atom Silver Clusters via Electron Transfer in Isostructural Redox-Active Porous Ionic Crystals.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202300743
Abstract: Ag clusters with a controlled number of atoms have received significant interest because they show size-dependent catalytic, optical, electronic, or magnetic properties. However, the synthesis of size-controlled, ligand-free, and air-stable Ag clusters with high yields… read more here.
Keywords: electron transfer; size; porous ionic; size controlled ... See more keywords
Click-Based Porous Ionic Polymers with Intercalated High-Density Metalloporphyrin for Sustainable CO2 Transformation
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DOI: 10.1021/acs.iecr.0c03766
Abstract: The development of advanced charged polymers with multifunctionality for heterogeneous catalysis is glamorous but still challenging. Herein, on the basis of function-oriented design philosophy, a s... read more here.
Keywords: click based; porous ionic; intercalated high; based porous ... See more keywords
Oxygen Evolution Reaction Driven by Charge Transfer from a Cr Complex to Co-Containing Polyoxometalate in a Porous Ionic Crystal.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10471
Abstract: Considerable efforts have been devoted to developing oxygen evolution reaction (OER) catalysts based on transition metal oxides. Polyoxometalates (POMs) can be regarded as model compounds of transition metal oxides, and cobalt-containing POMs (Co-POMs) have received… read more here.
Keywords: oxygen evolution; transfer; reaction; charge transfer ... See more keywords
ZIF-8-porous ionic liquids for the extraction of 2,2,3,3-tetrafluoro-1-propanol and water mixture
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DOI: 10.1039/d1nj01053k
Abstract: The design of stable ionic liquids (ILs) has become crucial for efficient liquid–liquid extraction (LLE) of alcohol and water. Porous ionic liquids (PILs), as a special class of ILs, have attracted attention by virtue of… read more here.
Keywords: zif; water; tetrafluoro propanol; porous ionic ... See more keywords
Incorporating highly basic polyoxometalate anions comprising Nb or Ta into nanoscale reaction fields of porous ionic crystals.
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DOI: 10.1039/d1nr04762k
Abstract: Polyoxometalates (POMs) are oxide cluster anions composed of high-valence early transition metals and are widely used as catalysts. Yet base catalysis of POMs remains an ongoing challenge; group V (V, Nb, and Ta) elements form… read more here.
Keywords: porous ionic; basic polyoxometalate; ionic crystals; reaction ... See more keywords
Basicity of isostructural porous ionic crystals composed of Nb/Ta-substituted Keggin-type polyoxotungstates.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00478j
Abstract: Three isostructural porous ionic crystals (PICs) based on Keggin-type POMs with different compositions but equal negative charge ([BW12O40]5- (BW12), [SiW11NbO40]5- (SiW11Nb), and [SiW11TaO40]5- (SiW11Ta)) are synthesized. Experimental and theoretical characterizations of the three PICs (1_BW12,… read more here.
Keywords: basicity isostructural; crystals composed; ionic crystals; keggin type ... See more keywords