Mechanical behaviour of porous lanthanide oxide microspheres: Experimental investigation and numerical simulations
Sign Up to like & getrecommendations! Published in 2018 at "Journal of The European Ceramic Society"
DOI: 10.1016/j.jeurceramsoc.2017.09.024
Abstract: Abstract Actinide oxide microspheres are considered as promising substituents to powder precursors for the production of ceramic pellets of nuclear fuel or targets. Porous microspheres of sub-millimetric size are synthesised using the Weak Acid Resin… read more here.
Keywords: oxide microspheres; behaviour porous; lanthanide oxide; porous lanthanide ... See more keywords
A Series of 3D Porous Lanthanide-Substituted Polyoxometalate Frameworks Based on Rare Hexadecahedral {Ln6W8O28} Heterometallic Cage-Shaped Clusters.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02413
Abstract: A series of 3D porous lanthanide-substituted polyoxometalate frameworks, Na2[Ln2(H2O)11]2[Ln3(H2O)3(α-SiW11O39)2]2·69H2O (1-Ln, Ln = Sm, Eu, Gd, Tb, and Dy), are built from novel hexadecahedral {Ln6W8O28} heterometallic cage-shaped clusters. Intriguingly, every tetrameric {[Ln3(H2O)3(α-SiW11O39)2]2}14- cage-cluster is linked with… read more here.
Keywords: series porous; porous lanthanide; substituted polyoxometalate; lanthanide substituted ... See more keywords
Porous lanthanide metal–organic frameworks with metallic conductivity
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2205127119
Abstract: Significance No reported material both is intrinsically porous and conducts electricity like a metal. This incompatibility appears to be rooted in the fundamental mechanisms responsible for metallic charge transport. Here, we identified one class of… read more here.
Keywords: porous lanthanide; organic frameworks; conductivity; metal organic ... See more keywords