Continuous-Flow Catalysis Using Phosphine-Metal Complexes on Porous Polymers: Designing Ligands, Pores, and Reactors.
Sign Up to like & getrecommendations! Published in 2024 at "ChemPlusChem"
DOI: 10.1002/cplu.202400039
Abstract: Continuous-flow syntheses using immobilized catalysts can offer efficient chemical processes with easy separation and purification. In particular, porous polymers have gained significant interests for their applications to catalytic systems in the field of organic chemistry.… read more here.
Keywords: chemistry; continuous flow; phosphine metal; metal complexes ... See more keywords
Synthesis of Porous Sulfonamide Polymers by Capturing Atmospheric Sulfur Dioxide.
Sign Up to like & getrecommendations! Published in 2018 at "ChemSusChem"
DOI: 10.1002/cssc.201800572
Abstract: The emission of SO2 from the burning of fossil fuel has resulted in a severe atmospheric pollution. The development of efficient strategies for not only capturing but also utilizing SO2 is highly welcome. A simple,… read more here.
Keywords: sulfonamide polymers; porous polymers; synthesis porous; porous sulfonamide ... See more keywords
Thiol‐Functionalized Organic Porous Polymers as a Support for Gold Nanoparticles and Its Catalytic Applications
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201700044
Abstract: In this work, a novel synthesis approach of gold nanohybrid materials (Au/SH-OPPs) is demonstrated using the thiol-functionalized organic porous polymers (SH-OPPs) as a support by a combination of hyper-cross-linking and molecular templating of functionalized bottlebrush… read more here.
Keywords: thiol functionalized; porous polymers; organic porous; functionalized organic ... See more keywords
Advances in conjugated porous polymers via high internal phase emulsion templating
Sign Up to like & getrecommendations! Published in 2025 at "Polymer International"
DOI: 10.1002/pi.70042
Abstract: Functional porous materials hold significant promise across diverse technological applications, including heterogeneous catalysis, optoelectronics, energy storage, chemical sensors and gas separation. While efforts to replicate the properties of naturally occurring inorganic materials like zeolites and… read more here.
Keywords: conjugated porous; phase emulsion; internal phase; high internal ... See more keywords
Extending Conjugation Lengths of the Linkage Units in Triazine‐Based Porous Polymers for Enhanced Photocatalysis
Sign Up to like & getrecommendations! Published in 2024 at "Small Methods"
DOI: 10.1002/smtd.202401744
Abstract: Three triazine‐based conjugated porous polymers (CPPs) are synthesized via a Pd‐catalyzed Suzuki‐Miyaura coupling reaction between derivatives of 2,4,6‐tri(thiophen‐2‐yl)‐1,3,5‐triazine (TTT) and 2,4,6‐triphenyl‐1,3,5‐triazine (TPT). Photocatalysis experiments demonstrate that the hydrogen evolution rate (HER) of ThTh‐CPP (homopolymer of… read more here.
Keywords: porous polymers; units triazine; triazine based; linkage units ... See more keywords
Porous polymers via emulsion templating: pore deformation during solidification cannot be explained by an osmotic transport!
Sign Up to like & getrecommendations! Published in 2020 at "Colloid and Polymer Science"
DOI: 10.1007/s00396-020-04678-5
Abstract: Using microfluidics, we were able to synthesize monodisperse water-in-monomer emulsions with styrene and divinylbenzene (DVB) as monomers. When polymerizing and drying these emulsions, we found that the structure of the resulting macroporous polymer strongly depends… read more here.
Keywords: osmotic transport; mechanism; porous polymers; via emulsion ... See more keywords
Amphiphilic fluorinated block-copolymer coating for the preparation of hydrophobic porous materials
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Polymer Research"
DOI: 10.1007/s10965-018-1602-7
Abstract: AbstractA new approach to the preparation of hydrophobic porous polymers has been proposed. Three series of porous polymers which pores equally well-absorbed as water and organic liquids (benzene and iso-octane) were synthesized by visible light… read more here.
Keywords: preparation hydrophobic; block copolymer; block; porous polymers ... See more keywords
Stimuli-responsive hybrid porous polymers based on acetals of polyvinyl alcohol and acrylic hydrogels
Sign Up to like & getrecommendations! Published in 2018 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2018.02.015
Abstract: Abstract Hybrid hydrogels have gained a lot of attention due to their unique properties which can be tailored for a variety of applications. In this paper, hybrid porous polymers based on sponge-like acetals of polyvinyl… read more here.
Keywords: hybrid porous; porous polymers; polymers based; polyvinyl alcohol ... See more keywords
Triptycene-based porous polymers regulated by diarylethenes
Sign Up to like & getrecommendations! Published in 2018 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2018.06.007
Abstract: Abstract Linear and star triptycene-based porous polymers regulated by diarylethenes were constructed via Pd (0)-catalyzed Suzuki coupling reaction, respectively. Both triptycene-based porous polymers performed reversible photochromism in solid state but exhibited distinctive solvent-dependent photochromism in… read more here.
Keywords: triptycene based; porous polymers; based porous; regulated diarylethenes ... See more keywords
Porous Polymers with Switchable Optical Transmittance for Optical and Thermal Regulation
Sign Up to like & getrecommendations! Published in 2019 at "Joule"
DOI: 10.1016/j.joule.2019.09.016
Abstract: Summary Adaptive control of broadband light is essential for diverse applications including building energy management and light modulation. Here, we present porous polymer coatings (PPCs), whose optical transmittance changes upon reversible wetting with common liquids,… read more here.
Keywords: porous polymers; optical transmittance; switchable optical; optical thermal ... See more keywords
Hybrid porous polymers based on cage-like organosiloxanes: synthesis, properties and applications
Sign Up to like & getrecommendations! Published in 2021 at "Progress in Polymer Science"
DOI: 10.1016/j.progpolymsci.2021.101419
Abstract: Abstract Cage-like organosiloxanes have proven to be ideal 3D building blocks for constructing unique classes of covalently-linked hybrid porous polymers with tunable structures and multifunctional properties for numerous applications. Since their discovery in 1990, hybrid… read more here.
Keywords: porous polymers; hybrid porous; polymers based; cage like ... See more keywords