Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: Esterification and decarboxylation dual pathway
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron"
DOI: 10.1016/j.tet.2021.132377
Abstract: Abstract A dual-functional copper porphyrin-catalyzed cross dehydrogenative coupling (CDC) of carboxylic acids with alkanes was reported firstly. The reaction gives allylic esters or alkylalkenes depending on the carboxylic acid substrates. Copper porphyrin catalyzed CDC method… read more here.
Keywords: copper porphyrin; cross dehydrogenative; catalyzed cross; porphyrin catalyzed ... See more keywords
Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.0c00044
Abstract: ConspectusThe oxygen reduction reaction (ORR) is a multiproton/multielectron transformation in which dioxygen (O2) is reduced to water or hydrogen peroxide and serves as the cathode reaction in most fuel cells. The ORR (O2 + 4e-… read more here.
Keywords: scaling relationships; porphyrin catalyzed; reaction; molecular scaling ... See more keywords
Cu(II) Porphyrin-catalyzed Coupling of Alkyl Tosylates and Grignard Reagents
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DOI: 10.1246/cl.200064
Abstract: Copper(II) porphyrin-catalyzed coupling of alkyl tosylates and alkyl Grignard reagents afforded substituted alkanes. The role of the copper(II) porphyrin complex was examined using EPR and in-situ ... read more here.
Keywords: grignard reagents; alkyl tosylates; porphyrin catalyzed; coupling alkyl ... See more keywords