Highly Coupled Heterobicycle-Fused Porphyrin Dimers -Excitonic Coupling and Charge Separation with Coordinated Fullerene, C60.
Sign Up to like & getrecommendations! Published in 2023 at "ChemSusChem"
DOI: 10.1002/cssc.202202289
Abstract: Porphyrin dimers have been widely explored and studied owing to their importance in photosynthetic systems. A vast variety of dimers linked by different groups and at different angles have been synthesized and studied; however, the… read more here.
Keywords: charge separation; charge; porphyrin dimers; excitonic coupling ... See more keywords
Chiral Modulation from Molecular to Macroscopic levels by synthetic chiral-amide-bonded porphyrin dimers
Sign Up to like & getrecommendations! Published in 2019 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2019.107637
Abstract: Abstract Six different nanoarchitectures were constructed by a series of synthetic bio-inspired chiral porphyrin dimers through molecular self-assembly behaviour. A plausible mechanism of chiral expression from the molecular to the macroscopic levels was investigated through… read more here.
Keywords: porphyrin dimers; macroscopic levels; chiral modulation; modulation molecular ... See more keywords
Covalent bonds immobilization of cofacial Mn porphyrin dimers on an ITO electrode for efficient water oxidation in aqueous solutions
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2017.05.018
Abstract: Abstract We previously reported several manganese porphyrin dimers as the first manganese-containing molecular catalysts for water oxidation, however, in non-aqueous CH 3 CN solution containing 5% H 2 O. Here, we successfully fabricated these dimers… read more here.
Keywords: porphyrin dimers; water; water oxidation; ito electrode ... See more keywords
Synthetic Control of Exciton Dynamics in Bioinspired Cofacial Porphyrin Dimers.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12889
Abstract: Understanding how the complex interplay among excitonic interactions, vibronic couplings, and reorganization energy determines coherence-enabled transport mechanisms is a grand challenge with both foundational implications and potential payoffs for energy science. We use a combined… read more here.
Keywords: cofacial porphyrin; coherence; exciton dynamics; porphyrin dimers ... See more keywords
Macroscopically Anisotropic Structures Produced by Light-induced Solvothermal Assembly of Porphyrin Dimers
Sign Up to like & getrecommendations! Published in 2018 at "Scientific Reports"
DOI: 10.1038/s41598-018-28311-2
Abstract: Porphyrin-based molecules play an important role in natural biological systems such as photosynthetic antennae and haemoglobin. Recent organic chemistry provides artificial porphyrin-based molecules having unique electronic and optical properties, which leads to wide applications in… read more here.
Keywords: porphyrin dimers; induced solvothermal; light induced; anisotropic structures ... See more keywords
Conjugated D-A porphyrin dimers for solution-processed bulk-heterojunction organic solar cells.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc00489c
Abstract: Three conjugated D-A porphyrin dimers (DPP-ZnP-E)2, (DPP-ZnP-E)2-2T and (DPP-ZnP-E)2-Ph linked with diethynylene, diethynylene-dithiophene and diethynylene-phenylene have been developed for bulk heterojunction solar cells with high power conversion efficiencies of 4.50%, 5.50% and 6.42%, respectively, when… read more here.
Keywords: dpp znp; conjugated porphyrin; porphyrin dimers; bulk heterojunction ... See more keywords
Synthesis of Phosphole-bridged Porphyrin Dimers
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry Letters"
DOI: 10.1246/cl.180943
Abstract: We synthesized phosphole-bridged porphyrin dimers and evaluated their optical and electrochemical properties. The porphyrin dimers exhibited broadened and red-shifted absorption relative to thienyl... read more here.
Keywords: porphyrin dimers; synthesis phosphole; phosphole bridged; chemistry ... See more keywords
Helically Twisted Benzene-1,3,5-triamine-fused Porphyrin Dimers
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry Letters"
DOI: 10.1246/cl.200115
Abstract: NiII-2,18-dibromo-20-chloroporphyrin was fused with N1,N3,N5-triaryl-1,3,5-benzenetriamine via t-BuONa-promoted one-pot reaction to give a helically twisted nitrogen-doped fused porphyrin dimer wit... read more here.
Keywords: porphyrin dimers; twisted benzene; triamine fused; fused porphyrin ... See more keywords
Self-Assembly of Covalently Linked Porphyrin Dimers at the Solid–Liquid Interface
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24163018
Abstract: The synthesis and surface self-assembly behavior of two types of metal-porphyrin dimers is described. The first dimer type consists of two porphyrins linked via a rigid conjugated spacer, and the second type has an alkyne… read more here.
Keywords: porphyrin dimers; self assembly; dimers solid; liquid interface ... See more keywords