Origin of the Distinctive Electronic Structure of Co- and Fe-Porphyrin-Nitrene and Its Effect on Their Nitrene Transfer Reactivity.
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DOI: 10.1021/acs.inorgchem.3c00463
Abstract: Metal-bound nitrene species are the crucial intermediate in catalytic nitrene transfer reactions exhibited by engineered enzymes and molecular catalysts. The electronic structure of such species and its correlation with nitrene transfer reactivity have not been… read more here.
Keywords: porphyrin nitrene; nitrene; nitrene transfer; electronic structure ... See more keywords