Post-functionalization of perfluorocyclobutyl aryl ether polymers with a novel perfluorosulfonated side chain precursor
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Polymer Research"
DOI: 10.1007/s10965-019-1782-9
Abstract: AbstractTo develop a new approach to prepare sulfonated perfluorocylobutyl (PFCB) aryl ether polymers, post-functionalization of PFCB aryl ether polymers with a novel perfluorosulfonated side chain precursor was described in this study. The precursor was firstly… read more here.
Keywords: aryl ether; perfluorosulfonated side; post functionalization; precursor ... See more keywords
Copolymerization of azide-containing carbonate with lactide and post functionalization
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Polymer Research"
DOI: 10.1007/s10965-020-02117-1
Abstract: The intention of this work was to study the polymerization of a cyclic carbonate monomer bearing one azido group, i.e. 2-(azidemethyl)-2-methyltrimethylene carbonate (AMTC), to disclose the characteristics of the resulted polymers and to explore the… read more here.
Keywords: reaction; post functionalization; copolymerization; carbonate ... See more keywords
Synthesis and Post-Functionalization of Poly(conjugated ester)s Based on 3-Methylene-1,5-dioxepan-2-one.
Sign Up to like & getrecommendations! Published in 2022 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.2c01015
Abstract: Poly(α-methylene ester)s are an attractive type of functional aliphatic polyesters that represent a platform for the fabrication of various biodegradable and biomedical polymers. Herein, we report the controlled ring-opening polymerization (ROP) of a seven-membered α-methylene… read more here.
Keywords: methylene; post functionalization; methylene dioxepan; synthesis post ... See more keywords
Post-Functionalization of Porous Organic Polymers Based on the Friedel-Crafts Acylation for CO2 and Hg2+ Capture.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c11180
Abstract: Melamine-based porous organic polymers (POPs) are promising for gas uptake and water treatment for their unique and tunable porosity, high nitrogen (N) content, and high Brunauer-Emmett-Teller (BET) surface area (SBET). However, it is difficult to… read more here.
Keywords: organic polymers; porous organic; post functionalization; crafts acylation ... See more keywords
Post-functionalization of polyethers by photoinduced C–H amidation via polar-radical relay
Sign Up to like & getrecommendations! Published in 2025 at "Nature Communications"
DOI: 10.1038/s41467-025-63254-z
Abstract: The C–H functionalization of polymers enables the direct incorporation of new functional groups into polymer backbones, presenting significant opportunities for the upcycling of commodity polymers. However, developing reactions that achieve selective functionalization while preserving the… read more here.
Keywords: photoinduced amidation; polar radical; post functionalization; functionalization ... See more keywords
Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01543g
Abstract: A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate,… read more here.
Keywords: tri substituted; post functionalization; mixed valence; tri ... See more keywords
The post-functionalization of Co(iii)PPh3 triarylcorroles through Suzuki-Miyaura couplings and their tunable electrochemically-catalyzed hydrogen evolution and oxygen reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04917g
Abstract: The post-functionalization of six novel symmetric and asymmetric meso-expanded Co(iii) corroles through Suzuki-Miyaura coupling reactions has been successfully accomplished and is reported along with their structural characterization. An analysis of the structure-property relationships of the… read more here.
Keywords: suzuki miyaura; functionalization; post functionalization; oxygen reduction ... See more keywords
Milestones in corrole chemistry: historical ligand syntheses and post-functionalization.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d1cs01137e
Abstract: Corroles are synthetic porphyrin analogs that contain one meso carbon atom lesser and bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry, demonstrate unique coordination chemistry and have impressive and diverse physical properties,… read more here.
Keywords: milestones corrole; corrole chemistry; chemistry; post functionalization ... See more keywords
Synthesis, Post-Functionalization, and Photoluminescence of Contorted Diazaphosphepine-Based Polycyclic Aromatic Heterocycles
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00958k
Abstract: Heteratom-doped organic π-conjugated molecules (OCMs) have become one type of emerging optoelectronic materials with intriguing functionalities. Phosphorus (P)-doped OCMs are a special member of the heteratom-doped OCMs where rich P-chemistry... read more here.
Keywords: post functionalization; diazaphosphepine based; contorted diazaphosphepine; photoluminescence contorted ... See more keywords
Rational synthesis of elusive organic–inorganic hybrid metal-oxo clusters: formation and post-functionalization of hexavanadates
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00038a
Abstract: Paving the way towards new functional materials relies increasingly on the challenging task of forming organic–inorganic hybrid compounds. In that regard, discrete atomically-precise metal-oxo nanoclusters have received increasing attention due to the wide range of… read more here.
Keywords: metal oxo; functionalization; post functionalization;
Post-Functionalization of End-Capping Twistacenes with Pyrene Units
Sign Up to like & getrecommendations! Published in 2024 at "Organic Chemistry Frontiers"
DOI: 10.1039/d4qo01199f
Abstract: The size, shape, edge structure of nanographenes can significantly affect their physical properties. Meanwhile, the introduction of pentagon, heptagon, octagon into the parent nanographenes, along with various heterorings might result... read more here.
Keywords: pyrene units; capping twistacenes; post functionalization; functionalization end ... See more keywords