Articles with "post polymerization" as a keyword



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Poly(Pentafluorophenyl Methacrylate)-Based Nano-Objects Developed by Photo-PISA as Scaffolds for Post-Polymerization Functionalization.

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Published in 2019 at "Macromolecular rapid communications"

DOI: 10.1002/marc.201800460

Abstract: The preparation of a functional fluorine-containing block copolymer using reversible addition-fragmentation chain-transfer dispersion polymerization in DMSO as a "platform/scaffold" is explored. The nanostructures, comprised of poly(ethyleneglycol)-b-poly(pentafluorophenyl methacrylate) or PEG-b-P(PFMA), are formulated via photo-initiated polymerization-induced self-assembly… read more here.

Keywords: post polymerization; polymerization; pentafluorophenyl methacrylate; photo ... See more keywords
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Preparation of Functional Long‐Subchain Hyperbranched Polystyrenes via Post‐polymerization Modification: Study on the Critical Role of Chemical Stability of Branching Linkage

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Published in 2020 at "ChemistryOpen"

DOI: 10.1002/open.202000143

Abstract: Abstract Post‐polymerization modification (PPM) is one of the most powerful strategy for preparing polymers with functional groups that cannot be synthesized by direct polymerization. So far, numerous experimental efforts have been devoted to the stability… read more here.

Keywords: post polymerization; hyperbranched polystyrenes; subchain hyperbranched; long subchain ... See more keywords
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Post-polymerization reactivity of free radicals trapped in resin-based dental restorative materials by ESR spectroscopy

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Published in 2019 at "Polymer Bulletin"

DOI: 10.1007/s00289-019-02914-9

Abstract: The propagating and allylic free radicals generated when polymerizing dimethacrylate resin-based materials used in dentistry are detected by electron spin resonance (ESR) spectroscopy as a nine-line spectrum. This study aimed to probe their post-polymerization reactivity… read more here.

Keywords: free radicals; post polymerization; resin; spectroscopy ... See more keywords
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Combinatorial approaches in post-polymerization modification for rational development of therapeutic delivery systems.

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Published in 2018 at "Acta biomaterialia"

DOI: 10.1016/j.actbio.2018.04.010

Abstract: The combinatorial polymer library approach has been proven to be effective for the optimization of therapeutic delivery systems. The library of polymers with chemical diversity has been synthesized by (i) polymerization of functionalized monomers or… read more here.

Keywords: post polymerization; polymerization; delivery; therapeutic delivery ... See more keywords
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Synthesis of graphene-like ultrathin polyaniline and its post-polymerization coating on nanosilica leading towards superhydrophobicity of composites

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Published in 2017 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2016.11.027

Abstract: Abstract The present work reveals the formation of self-assembled graphene-like thin layered structure of electrochemically synthesized polyaniline (PAni) of thickness less than 4 nm. The nano-layered PAni sheets undergo transformation into squeezed macrorod-like structures which again… read more here.

Keywords: post polymerization; polymerization coating; towards superhydrophobicity; pani ... See more keywords
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Post-polymerization modification of polymeric active esters towards TEMPO containing polymers: A systematic study

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Published in 2020 at "European Polymer Journal"

DOI: 10.1016/j.eurpolymj.2020.109660

Abstract: Abstract Organic radical batteries (ORB) are a novel promising class for energy storage, particularly featuring a fast charging capability and extraordinary cycle life. The representative polymer, i.e. poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA), is usually synthesized by a… read more here.

Keywords: containing polymers; post polymerization; post; tempo containing ... See more keywords
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Photophysical properties of soluble light-harvesting polyhydrofurans from post-polymerization functionalization of polyketones

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Published in 2021 at "European Polymer Journal"

DOI: 10.1016/j.eurpolymj.2021.110302

Abstract: Abstract Soluble polyhydrofurans with chromophoric end-groups have been synthesized via post-polymerization modifications of polyketones. The absorption intensity in solution and molecular weight were controlled by manipulation of reaction time after addition of HBr gas, and… read more here.

Keywords: properties soluble; photophysical properties; post polymerization; end groups ... See more keywords
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Synthesis of multifunctional homopolymers via sequential post-polymerization reactions

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Published in 2018 at "Polymer Chemistry"

DOI: 10.1039/c8py01055b

Abstract: Multifunctional homopolymers, homopolymers with multiple pendent functionalities, can offer unparalleled properties not possible with traditional polymers. Preparation of multifunctional homopolymers has been a challenge, but one promising approach involves sequential and selective post-polymerization modification of… read more here.

Keywords: homopolymers via; post polymerization; synthesis multifunctional; multifunctional homopolymers ... See more keywords
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Post-polymerization modification of polybenzoxazines with boronic acids supported by B–N interactions

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Published in 2021 at "Polymer Chemistry"

DOI: 10.1039/d1py00657f

Abstract: Polybenzoxazines (PBZs) were modified using the reactivity of their inherent bis(2-hydroxybenzyl)amine (BHBA) units toward boronic acids, RB(OH)2. read more here.

Keywords: post polymerization; boronic acids; polybenzoxazines boronic; polymerization modification ... See more keywords
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Tunable control of the performance of aqueous-based electrochemical devices by post-polymerization functionalization.

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Published in 2023 at "Materials horizons"

DOI: 10.1039/d3mh00418j

Abstract: Functionalized polymeric mixed ionic-electronic conductors (PMIECs) are highly desired for the development of electrochemical applications, yet are hindered by the limited conventional synthesis techniques. Here, we propose a "graft-onto-polymer" synthesis strategy by post-polymerization functionalization (GOP-PPF)… read more here.

Keywords: post polymerization; polymerization functionalization; performance;
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Amphiphilic Polypeptides Obtained by the Post-Polymerization Modification of Poly(Glutamic Acid) and Their Evaluation as Delivery Systems for Hydrophobic Drugs

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Published in 2023 at "International Journal of Molecular Sciences"

DOI: 10.3390/ijms24021049

Abstract: Synthetic poly(amino acids) are a unique class of macromolecules imitating natural polypeptides and are widely considered as carriers for drug and gene delivery. In this work, we synthesized, characterized and studied the properties of amphiphilic… read more here.

Keywords: obtained post; modification poly; poly glutamic; glutamic acid ... See more keywords