Articles with "post synthetic" as a keyword



Post‐Synthetic Amide Insertion Into Polyethylenes Augments Diverse Physical Properties and Enables Branching‐Dependent Recyclability

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Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202513841

Abstract: Polyethylenes (PEs) possess unreactive saturated hydrocarbon backbones, which make chemical recycling highly challenging, even at high temperatures. The insertion of strongly‐hydrogen‐bonding amide linkages into the PE backbone can potentially confer recyclability via amide cleavage and… read more here.

Keywords: branching dependent; amide insertion; post synthetic; recyclability ... See more keywords

Enhancing Photocatalytic Activity of Porous Organic Frameworks via Facile Post‐Synthetic Modification for Ultrafast Uranium Extraction

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Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202519249

Abstract: The design of heterogeneous photocatalysts, especially those utilizing advanced porous organic frameworks, has recently attracted considerable interest for their ability to efficiently convert solar energy into chemical energy by harnessing water as a sustainable electron… read more here.

Keywords: post synthetic; organic frameworks; photocatalytic activity; porous organic ... See more keywords

A Post‐synthetic Exchange/Deprotection Approach to Append Aliphatic Amines in Defective UiO‐66

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Published in 2025 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202500110

Abstract: Aliphatic amine‐functionalised metal‐organic frameworks (MOFs) are receiving increasing attention for their potential as adsorbents for CO2. In this work, we present a two‐step post‐synthetic approach, applied to defective ZrIV‐based MOF UiO‐66, that involves the exchange… read more here.

Keywords: post synthetic; synthetic exchange; deprotection; approach ... See more keywords

Linker Exchange as facile method for post-synthetic modification of ß-ketoenamine linked Covalent Organic Frameworks.

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Published in 2023 at "Macromolecular rapid communications"

DOI: 10.1002/marc.202300046

Abstract: Post-synthetic linker exchange performed on covalent organic frameworks (COFs) has become an important method to introduce functional building blocks into their backbone and thus to tune their chemical and physical properties. However, the linker exchange… read more here.

Keywords: linker exchange; exchange; post synthetic; method ... See more keywords
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Influence of post-synthetic modifications on the composition, acidity and textural properties of ZSM-22 zeolite

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Published in 2018 at "Catalysis Today"

DOI: 10.1016/j.cattod.2017.04.042

Abstract: Abstract In this work, an extensive investigation of the preparation of a large body of desilicated ZSM-22 zeolites and their basic characterization is presented. We investigate the effects of the properties of the starting zeolite,… read more here.

Keywords: post synthetic; modifications composition; composition acidity; synthetic modifications ... See more keywords

Post synthetic modification of Zr-MOF with phenylboronic acid: Fluorescence sensing of sialic acid

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Published in 2022 at "Dyes and Pigments"

DOI: 10.1016/j.dyepig.2021.109839

Abstract: Abstract Luminescent metal-organic frameworks (LMOFs) have become an important class of fluorescence sensing materials, whereas direct applications of LMOF for identifying analytes still remain a challenge. Post synthetic modification (PSM) is an effective strategy to… read more here.

Keywords: post synthetic; fluorescence; synthetic modification; fluorescence sensing ... See more keywords
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Post-synthetic Ti exchanged UiO-66-NH2 metal-organic frameworks with high faradaic efficiency for electrochemical nitrogen reduction reaction

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Published in 2021 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2021.07.079

Abstract: Abstract Electrochemical nitrogen reduction reaction (NRR) is a promising approach for NH3 production to take place of the traditional Haber-Bosch process, which is still limited by the low NH3 yield rate and low Faradaic efficiency.… read more here.

Keywords: electrochemical nitrogen; post synthetic; faradaic efficiency; reduction reaction ... See more keywords
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Significant improvement in antibacterial property of ZIF-8 decorated graphene oxide by post-synthetic modification process

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Published in 2021 at "Journal of environmental chemical engineering"

DOI: 10.1016/j.jece.2021.105887

Abstract: Abstract The effects of different ammonium hydroxide loadings towards morphological and antibacterial properties of ZGO composites in a straightforward post synthetic-modification were comprehensively investigated. Fourier Transform Infrared Spectroscopy (FTIR) result indicated a successful modification of… read more here.

Keywords: synthetic modification; modification; significant improvement; post synthetic ... See more keywords
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Effect of bacterial nanocellulose post-synthetic processing on powders and rehydrated suspensions characteristics

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Published in 2020 at "Journal of Food Engineering"

DOI: 10.1016/j.jfoodeng.2020.109994

Abstract: Abstract Bacterial nanocellulose (BNC) is synthetized as hydrated sheets difficult to mix or store and commercialize. Therefore, to incorporate in food matrices, BNC should be previously processed to obtain powders easily resuspended, which are able… read more here.

Keywords: nanocellulose post; post synthetic; synthetic processing; effect bacterial ... See more keywords

Synthesis and post-synthetic modification of UiO-67 type metal-organic frameworks by mechanochemistry

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Published in 2017 at "Materials Letters"

DOI: 10.1016/j.matlet.2017.03.140

Abstract: Abstract Herein, we report the synthesis of zirconium metal-organic frameworks by a mechanochemical route. The frameworks are obtained by the coordination of a zirconium cluster with the biphenyldicarboxylic acid linker to obtain UiO-67 or with… read more here.

Keywords: organic frameworks; synthetic modification; post synthetic; metal organic ... See more keywords

Post-synthetic modification of MIL-125 with bis-quinoline Mannich bases for removal of heavy metals from wastewater

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Published in 2019 at "Microporous and Mesoporous Materials"

DOI: 10.1016/j.micromeso.2018.12.018

Abstract: Abstract Ti-based metal-organic frameworks (NH2-MIL-125) were post synthetic modified through a facile strategy using bis-quinoline Mannich bases producing MIL-125-HQ. The modified material (MIL-125-HQ) was used as an absorbent for uptake of the heavy metals from… read more here.

Keywords: mil 125; quinoline; mannich bases; bis quinoline ... See more keywords