Organocatalytic Synthesis of cis-2,3-Aziridine Aldehydes by a Postreaction Isomerization.
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DOI: 10.1021/acs.orglett.7b02634
Abstract: An unprecedented organocatalytic cis-selective aziridination of α,β-unsaturated aldehydes is described. The strategy utilizes postreaction isomerization as a key step. Our study demonstrates that by a proper choice of structural features of reagents and the catalyst… read more here.
Keywords: postreaction isomerization; organocatalytic synthesis; synthesis cis; cis ... See more keywords