Postsynthetic Modification of Metal-Organic Frameworks by Vapor-Phase Grafting.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00284
Abstract: A vapor-phase grafting strategy is developed for the postsynthetic modification of metal-organic frameworks (MOFs). On the basis of the Schotten-Baumann reaction between acyl chloride (-COCl) and amino (-NH2) groups and hydrolysis of -COCl, the carboxylated… read more here.
Keywords: phase grafting; postsynthetic modification; metal organic; vapor phase ... See more keywords
Trisequential Postsynthetic Modification of a Tagged IRMOF-9 Framework.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00862
Abstract: Tailoring the pore environments of metal-organic frameworks (MOFs) is key to improving their performance and expanding their applicability. Postsynthetic methods, wherein an already synthesized MOF undergoes further chemical reactions, present many advantages for such tailoring… read more here.
Keywords: postsynthetic modification; framework; chemistry; trisequential postsynthetic ... See more keywords
Functionalizing a Metal-Organic Framework by a Photoassisted Multicomponent Postsynthetic Modification Approach Showing Highly Effective Hg(II) Removal.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01457
Abstract: We present here the first use of a photoassisted multicomponent postsynthetic modification method to anchor a ZIF-90 scaffold with a pyrimidinethione fragment. The resultant materials, namely, ZIF-90-THP and ZIF-90-THF, show ultrahigh Hg(II) adsorption capacity values… read more here.
Keywords: functionalizing metal; postsynthetic modification; photoassisted multicomponent; metal organic ... See more keywords
Postsynthetic Modification: An Enabling Technology for the Advancement of Metal–Organic Frameworks
Sign Up to like & getrecommendations! Published in 2020 at "ACS Central Science"
DOI: 10.1021/acscentsci.0c00690
Abstract: Metal–organic frameworks (MOFs) are a class of porous materials with immense chemical tunability derived from their organic and inorganic building blocks. Presynthetic approaches have been used to construct tailor-made MOFs, but with a rather restricted… read more here.
Keywords: postsynthetic modification; psm; metal organic; metal ... See more keywords
Hydroboration of Hollow Microporous Organic Polymers: A Promising Postsynthetic Modification Method for Functional Materials.
Sign Up to like & getrecommendations! Published in 2022 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.2c00385
Abstract: This work shows that hydroboration can be efficiently applied to the postsynthetic modification (PSM) of the Sonogashira-Hagihara coupling-based microporous organic polymers (MOPs). Hollow MOPs (H-MOPs) were prepared by template synthesis through the Sonogashira-Hagihara coupling of… read more here.
Keywords: microporous organic; organic polymers; hydroboration hollow; postsynthetic modification ... See more keywords
Ab Initio Study of Hydrostable Metal–Organic Frameworks for Postsynthetic Modification and Tuning toward Practical Applications
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06658
Abstract: Metal–organic frameworks (MOFs), a subclass of nanoporous coordination polymers, have emerged as one of the most promising next-generation materials. The postsynthetic modification method, a strategy that provides tunability and control of these materials, plays an… read more here.
Keywords: gas; organic frameworks; metal organic; postsynthetic modification ... See more keywords
Enamine Approach for Versatile and Reversible Functionalization on Cellulose Related Porous Sponges
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b01369
Abstract: A readily modifiable cellulose sponge was prepared from cellulose acetoacetate (CAA). Facile postsynthetic modification with primary amino-containing modifiers such as octadecyl amine (ODA), cysteine (CYS), and l-glutamic acid (GLU) could be achieved demonstrating the ease… read more here.
Keywords: postsynthetic modification; enamine bonds; approach versatile; enamine approach ... See more keywords