Selective conversion of HMF into 3-hydroxymethylcyclopentylamine through a one-pot cascade process in aqueous phase over bimetallic NiCo nanoparticles as catalyst.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200194
Abstract: 5-hydroxymethylfurfural (HMF) has been successfully valorised into 3-hydroxymethyl cyclopentylamine through a one-pot cascade process in aqueous phase by coupling the hydrogenative ring-rearrangement of HMF into 3-hydroxymethylcyclopentanone (HCPN) followed by the reductive amination with ammonia. Mono… read more here.
Keywords: pot cascade; one pot; aqueous phase; hmf ... See more keywords
Physically mixed catalytic system of amino and sulfo-functional porous organic polymers as efficiently synergistic co-catalysts for one-pot cascade reactions
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj01357a
Abstract: In this article, acid/base bi-functional polymeric materials were prepared using physically mixed porous poly(divinylbenzene-co-4-vinylbenzenesulfonic acid) (P(DVB-VBS)) with sulfonic acid groups and poly(divinylbenzene-co-4-vinylbenzyl amine) (P(DVB-VBA)) with amino groups, which were synthesized by solvothermal polymerization of crosslinker… read more here.
Keywords: physically mixed; system; pot cascade; catalytic system ... See more keywords