Reaction of Diaryliodonium Salts with Potassium Alkyl Xanthates as an Entry Point to Accessing Organosulfur Compounds.
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DOI: 10.1021/acs.orglett.2c04143
Abstract: Preparation of S-aryl xanthates via transition-metal-catalyzed or SNAr reactions is complicated by their further transformations under the utilized conditions. In contrast, S-arylation of potassium O-alkyl xanthates with diaryliodonium salts proceeds under mild conditions, enabling access… read more here.
Keywords: potassium alkyl; organosulfur compounds; aryl xanthates; diaryliodonium salts ... See more keywords