One-Step Conversion of Potassium Organotrifluoroborates to Metal Organoborohydrides.
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DOI: 10.1021/acs.orglett.8b01373
Abstract: This letter describes the one-step conversion of heteroatom-substituted potassium organotrifluoroborates (KRBF3) to metal monoorganoborohydrides (MRBH3) using alkali metal aluminum hydrides. The method tolerates a variety of functional groups, expanding MRBH3 diversity. Hydride removal with Me3SiCl… read more here.
Keywords: step conversion; one step; potassium organotrifluoroborates;