Reversible Structural Transformation and Catalytic Potential of Lanthanide-Azobenzenetetracarboxylates.
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DOI: 10.1021/acs.inorgchem.2c00963
Abstract: Inspired by the catalytic potential of lanthanide coordination polymers of 3,3',5,5'-azobenzenetetracarboxylic acid (H4abtc), two new isostructural [Ln2III(Habtc)2(DMSO)4]·DMSO·H2O (LnIII = SmIII (I), EuIII = (II), DMSO = dimethyl sulfoxide) were synthesized and characterized. Their single-crystal structures… read more here.
Keywords: coordination; catalytic potential; potential lanthanide; structural transformation ... See more keywords