Planar-chiral ferrocenylphosphine-borane complexes featuring agostic-type B-HE (E = Hg, Sn) interactions.
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DOI: 10.1039/c6dt04791b
Abstract: The synthesis of ferrocenylphosphine-borane adducts 1,2-fc(E)(PPh2·BH3) (E = SnR2R', HgX; 1,2-fc = 1,2-ferrocenediyl) that are substituted with organotin or organomercury Lewis acid moieties in ortho-position is presented. Several compounds that feature two ferrocenylphosphine-borane moieties bridged… read more here.
Keywords: pph2; agostic type; pph2 bh3; ferrocenylphosphine borane ... See more keywords