Structure-Directing Effects of Counterions in Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates: 1D to Polycatenated 3D Species.
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DOI: 10.1021/acs.inorgchem.8b02762
Abstract: Nine uranyl ion complexes were synthesized under (solvo-)hydrothermal conditions using α,ω-dicarboxylic acids HOOC-(CH2) n-2-COOH (H2C n, n = 6-9) and diverse counterions. Complexes [PPh4][UO2(C6)(NO3)] (1) and [PPh4][UO2(C8)(NO3)] (2) contain zigzag one-dimensional (1D) chains, with further… read more here.
Keywords: directing effects; pph3me uo2; ion complexes; structure directing ... See more keywords