An eight-coordinate zinc complex containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvothermal synthesis, supramolecular structure and CSD studies
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DOI: 10.1016/j.molstruc.2018.06.063
Abstract: Abstract A new anionic coordination complex of Zn(II) containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylate (PDA), (H 3 O) 2 [Zn(PDA) 2 ]·2CH 3 NO 2 ·2H 2 O·( 1 ), has been synthesized by solvothermal… read more here.
Keywords: pre organized; complex containing; highly pre; ligand phenanthroline ... See more keywords
Efficient route to pre-organized and linear polyaminopolycarboxylates: Cy-TTHA, Cy-DTPA and mono/di- reactive, tert-butyl protected TTHA/Cy-TTHA.
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DOI: 10.1016/j.tetlet.2017.02.056
Abstract: Pre-organized polyaminopolycarboxylate chelators Cy-TTHA and Cy-DTPA were synthesized via modular five-step syntheses from commercially available starting materials in ~ 62% and 47% overall yields, respectively. Furthermore, strategies are reported for the efficient preparation of mono-… read more here.
Keywords: ttha dtpa; pre organized; ttha; tert butyl ... See more keywords
Chirality and spatially pre-organized multi-porphyrinoids
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DOI: 10.1142/s1088424618500396
Abstract: We report herein that chiral and enantiopure compounds such nucleosides and peptides can pre-organize multi-porphyrinic systems and influence their properties. The first example given concerns star... read more here.
Keywords: chirality spatially; pre organized; organized multi; spatially pre ... See more keywords