Articles with "precursors radicals" as a keyword



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Azodioxy compounds as precursors for C-radicals and their application in thermal styrene difunctionalization

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc03860a

Abstract: An atom-economic thermal α,β-difunctionalization of various styrenes with readily prepared azodioxy compounds is reported. Mechanistic studies reveal that the starting azodioxy compounds can thermally be cleaved to the corresponding C-nitroso compounds, which under these thermal… read more here.

Keywords: styrene; difunctionalization; precursors radicals; azodioxy compounds ... See more keywords