Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters
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DOI: 10.1021/acs.chemmater.2c00418
Abstract: Current nucleation models propose manifold options for the formation of crystalline materials. Exploring and distinguishing between different crystallization pathways on the molecular level however remain a challenge, especially for complex porous materials. These usually consist… read more here.
Keywords: nucleation porous; prenucleation clusters; ion paired; paired prenucleation ... See more keywords
Atomistic structures and dynamics of prenucleation clusters in MOF-2 and MOF-5 syntheses
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DOI: 10.1038/s41467-019-11564-4
Abstract: Chemical reactions in solution almost always take place via a series of minute intermediates that are often in rapid equilibrium with each other, and hence hardly characterizable at the level of atomistic molecular structures. We… read more here.
Keywords: prenucleation clusters; atomistic structures; structures dynamics; prenucleation ... See more keywords