Controlled preparation of amphiphilic triblock-copolyether in a metal- and solvent-free approach for tailored structure-directing agents.
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DOI: 10.1039/c7cc09031e
Abstract: Under mild conditions, PPO-PEO-PPO ("reverse Pluronics") and PBO-PEO-PBO copolyether were generated by way of N-heterocyclic olefin-based organocatalysis. Reverse Pluronics with molar masses > 20 000 g mol-1 could be synthesized with excellent control (ĐM ≤… read more here.
Keywords: preparation amphiphilic; amphiphilic triblock; controlled preparation; structure directing ... See more keywords