Copper Azide Nanoparticle-Encapsulating MOF-Derived Porous Carbon: Electrochemical Preparation for High-Performance Primary Explosive Film.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202107364
Abstract: It is highly desired but still remains challenging to design a primary explosive-based nanoparticle-encapsulated conductive skeleton for the development of powerful yet safe energetic films employed in miniaturized explosive systems. Herein, a proof-of-concept electrochemical preparation… read more here.
Keywords: copper; primary explosive; porous carbon; film ... See more keywords
Constructing Highly Reliable and Adaptive Primary Explosive Composites for Micro-Initiator Assisting by a Hybrid Template of Metal-Organic Frameworks and Cross-Linked Polymers.
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DOI: 10.1002/smll.202300157
Abstract: Primary explosive, as a reliable initiator for secondary explosives, is the central component of micro-initiators for modern aerospace systems and military operations. However, they are typically prepared as powders, posing potential safety risks because of… read more here.
Keywords: bulk material; primary explosive; cross linked; metal organic ... See more keywords
Planar, Energetic, π-π-Stacked Compound with Weak Interactions Resulting in a High-Impact- and Low-Friction-Sensitive, Safer, Primary Explosive.
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DOI: 10.1021/acs.inorgchem.9b00778
Abstract: 1,5-Diaminotetrazolecopper(I) nitrate ([Cu(DAT)3]NO3, CDN) was synthesized, and its structure was confirmed by single-crystal X-ray diffraction. Owing to its layered planar structure and weak π interactions between layers, CDN has a high-impact sensitivity of 1.5 J… read more here.
Keywords: planar; weak interactions; low friction; high impact ... See more keywords
An advanced primary explosive and secondary explosive based on a zwitterionic pyrazole-triazole derivative.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04531a
Abstract: Two zwitterionic energetic materials containing a pyrazole-triazole backbone were synthesized and fully characterized. Compound 3 can serve as an ideal secondary explosive due to its high decomposition temperature (>200 °C), low impact sensitivity (>40 J),… read more here.
Keywords: secondary explosive; primary explosive; pyrazole triazole; advanced primary ... See more keywords