A Silyl Sulfinylamine Reagent Enables the Modular Synthesis of Sulfonimidamides via Primary Sulfinamides
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DOI: 10.1021/acs.orglett.2c00347
Abstract: A new N-silyl sulfinylamine reagent allows the rapid preparation of a broad range of (hetero)aryl, alkenyl, and alkyl primary sulfinamides, using Grignard, organolithium, or organozinc reagents to introduce the carbon fragment. Treatment of these primary… read more here.
Keywords: reagent; primary sulfinamides; enables modular; silyl sulfinylamine ... See more keywords
Copper-Catalyzed, Aerobic Synthesis of NH-Sulfonimidamides from Primary Sulfinamides and Secondary Amines.
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DOI: 10.1021/acs.orglett.2c02804
Abstract: NH-Sulfonimidamides are prepared by copper-catalyzed coupling of primary sulfinamides with secondary amines. Neither a ligand nor an additive is needed, and air is the terminal oxidant. The reactions occur at room temperature, show good functional… read more here.
Keywords: primary sulfinamides; catalyzed aerobic; sulfinamides secondary; secondary amines ... See more keywords