Articles with "primary trifluoroborate" as a keyword



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Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d1sc07065g

Abstract: This work describes the first preparation and application of primary trifluoroborate-iminiums (pTIMs) as a new, easily accessible and valuable class of organoboron derivatives. An array of structurally diverse pTIMs was prepared from potassium acyltrifluoroborates in… read more here.

Keywords: primary trifluoroborate; aminoboronic acids; chiral aminoboronic; access chiral ... See more keywords