Chloride-Mediated Alkene Activation Drives Enantioselective Thiourea and Hydrogen Chloride Co-Catalyzed Prins Cyclizations.
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DOI: 10.1021/jacs.2c06688
Abstract: The mechanism of chiral hydrogen-bond donor (HBD) and hydrogen chloride (HCl) co-catalyzed Prins cyclizations was analyzed through a combination of experimental and computational methods and revealed to involve an unexpected and previously unrecognized mode of… read more here.
Keywords: catalyzed prins; hydrogen; prins cyclizations; chloride ... See more keywords