Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape.
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DOI: 10.1021/jacs.1c11857
Abstract: Herein we report the first chiral Au10 nanoclusters stabilized by chiral bis N-heterocyclic carbene (bisNHC) ligands. ESI-MS and single-crystal X-ray crystallography confirmed the molecular formula to be [Au10(bisNHC)4Br2](O2CCF3)2. The chiral Au10 nanocluster adopts a linear… read more here.
Keywords: chiral bis; edge shared; prolate shape; au10 nanocluster ... See more keywords