Significant Improvement on Enantioselectivity and Diastereoselectivity of Organocatalyzed Asymmetric Aldol Reaction Using Helical Polyisocyanides Bearing Proline Pendants
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DOI: 10.1021/acsmacrolett.7b00439
Abstract: A novel enantiopure phenyl isocyanide (1) carrying l-proline derivative was designed and synthesized. Living polymerization of 1 using a alkyne-Pd(II) catalyst affording a series of helical poly-1ms with controlled molecular weights (Mns) and narrow molecular… read more here.
Keywords: proline pendants; bearing proline; aldol reaction; poly ... See more keywords