Rhodium-Promoted C-H Activation/Annulation between DNA-Linked Terminal Alkyne and Aromatic Acid: A Finding from the Selection Outcomes.
Sign Up to like & getrecommendations! Published in 2024 at "Organic letters"
DOI: 10.1021/acs.orglett.4c01553
Abstract: Inspired by previous selection outcomes, we investigated and developed a rhodium-promoted C-H activation/annulation reaction of DNA-linked terminal alkynes and aromatic acids. This reaction exhibits excellent efficiency with high conversions and a broad substrate scope. Most… read more here.
Keywords: dna linked; selection outcomes; activation annulation; promoted activation ... See more keywords
Dimerizing cascades of enallenamides reveal the visible-light-promoted activation of cumulated C–C double bonds
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06719b
Abstract: The visible-light-promoted activation of conjugated C–C double bonds is well developed, while that of cumulated systems is underexplored. We present the feasibility of this challenging approach. The localization of a triplet on an allenamide arm… read more here.
Keywords: promoted activation; double bonds; light promoted; visible light ... See more keywords