Articles with "promoted asymmetric" as a keyword



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Palladacycle promoted asymmetric hydrophosphination of α,β-unsaturated sulfonyl fluorides

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Published in 2019 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2019.120912

Abstract: Abstract The first example of an enantioselective hydrophosphination reaction of ethenesulfonyl fluoride derivatives catalyzed by a phosphapalladacycle afforded chiral sulfonyl fluoride-derived phosphines in quantitative yields and enantioselectivities of up to 93% ee. Investigations revealed the… read more here.

Keywords: unsaturated sulfonyl; hydrophosphination; palladacycle promoted; asymmetric hydrophosphination ... See more keywords