Light-Promoted Dearylation of Perfluorinated Aryl Sulfides with N-Heterocyclic Carbene-Borane.
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DOI: 10.1021/acs.orglett.2c03585
Abstract: The removal of the tetrafluoropyridinyl group tethered to a sulfur atom using a complex of N-heterocyclic carbene (NHC) with borane is described. The reaction is performed under blue light irradiation with a disulfide as radical… read more here.
Keywords: borane; light promoted; promoted dearylation; dearylation perfluorinated ... See more keywords