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Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.09.054
Abstract: Abstract Enaminones are used as the key intermediates to construct heterocyclic compounds with various bioactivities. In this study, a simple and efficient approach for the synthesis of enaminones via amination of propargyl alcohols was developed.…
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Keywords:
silver catalyzed;
propargyl alcohols;
efficient synthesis;
catalyzed efficient ... See more keywords
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Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02049
Abstract: The Rh(III)-catalyzed dual directing group assisted C-H activation/annulation of 3-arylisoxazolones with propargyl alcohols has been developed, which expands the application scope of isoxazolones in organic synthesis. This protocol also worked well with 3-aryl-1,4,2-dioxazol-5-ones to produce…
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Keywords:
propargyl alcohols;
dioxazol ones;
iii catalyzed;
regioselective annulations ... See more keywords
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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01011
Abstract: A straightforward synthesis of pyrimidines via Au(III) or Au(I)/Lewis-acid-catalyzed cascade reactions of propargyl alcohols with 3-amino-benzo[d]isoxazoles is described. The propargyl amine intermediates are readily generated in situ via oxophilic activation of gold(III) or a Lewis…
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Keywords:
reactions propargyl;
propargyl alcohols;
acid;
alcohols amino ... See more keywords
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Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b00674
Abstract: The rhodium-catalyzed alkynylation of aryl carbamates with propargyl alcohols is described. This methodology can provide aryl acetylenes from aryl carbamates via C-O bond activation. The use of propargyl alcohols as alkynylating agents allows the use…
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Keywords:
propargyl alcohols;
rhodium catalyzed;
carbamates propargyl;
alkynylation aryl ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00334
Abstract: Quantitative conversion of racemic propargyl alcohols into optically active propargyl esters with up to 99% ee has been achieved by lipase/oxovanadium co-catalyzed dynamic kinetic resolution, which combines the lipase-catalyzed enantioselective esterification of the racemic substrates…
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Keywords:
lipase oxovanadium;
racemization;
propargyl alcohols;
oxovanadium catalyzed ... See more keywords
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Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra03540e
Abstract: The Meyer–Schuster rearrangement of propargyl alcohols or alkynols leading to α,β-unsaturated carbonyl compounds is well known. Yet, electrophilic halogenations of the same alkynols and their alkoxy, ester and halo derivatives are inconspicuous. This review on…
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Keywords:
propargyl alcohols;
electrophilic halogenations;
mixed dihaloenones;
halogenations propargyl ... See more keywords
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Published in 2017 at "Synthesis"
DOI: 10.1055/s-0036-1591735
Abstract: Multiple bond-forming cascade transformations and one-pot procedures are valuable tools in organic synthesis and drug discovery. These atom-economical processes provide rapid access to natural product-like scaffolds from simple precursors. Herein, we report on ruthenium-catalyzed one-pot…
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Keywords:
pot;
propargyl alcohols;
pot procedures;
one pot ... See more keywords