Copper-Catalyzed Silylation of Propargyl Carbonates: A General Entry to Allenylsilanes
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DOI: 10.1039/d3qo00371j
Abstract: A general and practical route for the silylation of propargyl car-bonates with silylboranes catalyzed by copper has been devel-oped. A wide range of propargyl carbonates with different substi-tution patterns including... read more here.
Keywords: catalyzed silylation; propargyl; silylation propargyl; propargyl carbonates ... See more keywords
Palladium-Catalyzed Regioselective Coupling of Secondary Propargyl Carbonates and Ethyl 2-(pyridin-2-yl)acetate Derivatives: Facile Access to C-3 Benzylated Indolizines
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DOI: 10.1055/s-0037-1609552
Abstract: A palladium-catalyzed ligand controlled regioselective coupling reaction of secondary propargyl carbonates and ethyl 2-(pyridin-2-yl)acetate derivatives has been described, leading to C-3 benzylated indolizines for the first time in moderate to good yields. DBFphos as the… read more here.
Keywords: regioselective coupling; secondary propargyl; palladium catalyzed; carbonates ethyl ... See more keywords