Palladium-Catalyzed Intermolecular 1,3-Dienylation of Propargyl Esters Involving the Insertion of SO2.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c00334
Abstract: A palladium-catalyzed three-component 1,3-dienylation of propargylic esters with DABSO and aryl iodides has been developed. This novel reductive cross-coupling reaction produces 2-sufonylated 1,3-dienes as single products in the presence of reductive metal Mn with high… read more here.
Keywords: dienylation; dienylation propargyl; catalyzed intermolecular; palladium catalyzed ... See more keywords
Cancer cell targeting driven by selective polyamine reactivity with glycine propargyl esters.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01934c
Abstract: Rapidly growing cancer cells have increased levels of intracellular polyamines compared to normal, healthy tissues. Based on the selective reactivity of glycine propargyl esters, probes were synthesized that show evidence for selective polyamine reactivity, which… read more here.
Keywords: reactivity glycine; glycine propargyl; reactivity; propargyl esters ... See more keywords