Asymmetric Borylative Propargylation of Ketones Catalyzed by a Copper(I) Complex.
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DOI: 10.1021/acs.orglett.8b03912
Abstract: A copper(I)-catalyzed asymmetric borylative propargylation of simple ketones was disclosed. Additive NaBARF was found to be pivotal to achieve excellent enantioselectivity. This reaction enjoyed advantages of broad substrate scope, good tolerance of functional groups, high… read more here.
Keywords: propargylation ketones; copper; ketones catalyzed; asymmetric borylative ... See more keywords