Formation of a Propeller-Shaped Ni4Ga3 Cluster Supported by Transmetalation of Cp* from Ga to Ni.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00344
Abstract: The reactivity of GaCp* toward different Ni0 olefin complexes is investigated. The reaction of GaCp* with [Ni(cdt)] (cdt = all-trans-1,5,9-cyclododecatriene) leads to simple adduct formation and the 18 valence electron (ve) compound [Ni(GaCp*)(cdt)] (1). In… read more here.
Keywords: gacp; dvds; propeller shaped; formation propeller ... See more keywords
Carboranethiol-Protected Propeller-Shaped Photoresponsive Silver Nanomolecule.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00186
Abstract: We report the synthesis, structural characterization, and photophysical properties of a propeller-shaped Ag21 nanomolecule with six rotary arms, protected with m-carborane-9-thiol (MCT) and triphenylphosphine (TPP) ligands. Structural analysis reveals that the nanomolecule has an Ag13… read more here.
Keywords: carboranethiol protected; silver atoms; silver; propeller shaped ... See more keywords
Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F-NMR
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c03737
Abstract: Two propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and… read more here.
Keywords: chiral co3y; chemistry; 19f nmr; chemosensory ... See more keywords
Trefoiled Propeller-Shaped Spiral Terpyridyl Metal-Organic Architectures.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01701
Abstract: Constructing exquisite and intricate molecular architectures is always the pursuit of chemists. In this report, the propeller-shaped trefoil structures S1 and S2 were successfully prepared by the stepwise self-assembly of predesigned tripodal metal-organic ligands, which… read more here.
Keywords: organic architectures; propeller shaped; metal organic; metal ... See more keywords
Propeller-Shaped, Triarylamine-Rich, and Dopant-Free Hole-Transporting Materials for Efficient n-i-p Perovskite Solar Cells.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b15423
Abstract: By introducing six triarylamine groups to a hexaphenylbenzene (HPB) or a hexakis(2-thienyl)benzene (HTB) core, two propeller-shaped, triarylamine-rich, and low-cost hole-transporting materials (HTMs), which are termed as HPB-OMe and HTB-OMe, respectively, with considerable hole mobility, were… read more here.
Keywords: shaped triarylamine; hole transporting; propeller shaped; solar cells ... See more keywords
A propeller-shaped perylene diimide hexamer as a nonfullerene acceptor for organic solar cells
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Materials Chemistry C"
DOI: 10.1039/c8tc03081b
Abstract: A novel propeller-shaped molecule (HPB-PDI6) with a hexaphenylbenzene (HPB) core and six peripheral PDI units was synthesized via Co2(CO)8-catalyzed cyclotrimerization and used as an acceptor for organic solar cells (OSCs). The intriguing geometry of the… read more here.
Keywords: organic solar; propeller shaped; hpb pdi6; propeller ... See more keywords
A persistent radical anion derived from a propeller-shaped perylene bisimide-carbazole pentad.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02042d
Abstract: Stabilizing reactive radical ions promises outstanding performances in photocatalysis, organic optoelectronics and photothermal therapies, but it remains a challenge. In this contribution, we firstly report a persistent radical anion (PBI˙--4Cz) derived from a propeller-shaped electron-deficient… read more here.
Keywords: persistent radical; radical anion; derived propeller; propeller shaped ... See more keywords
Emission Quenching in Tetraphenylfuran Crystal: Why This Propeller-Shaped Molecule Does Not Emit in the Condensed Phase
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27020522
Abstract: Due to their substantial fluorescence quantum yields in the crystalline phase, propeller-shaped molecules have recently gained significant attention as potential emissive materials for optoelectronic applications. For the family of cyclopentadiene derivatives, light-emission is highly dependent… read more here.
Keywords: quenching tetraphenylfuran; emission quenching; propeller shaped; state ... See more keywords