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Published in 2021 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2020.147927
Abstract: Abstract In heterogeneous catalysis, oxygen vacancies of metal oxides play a key role by modulating properties of coordination, electron states, electrical conductivity, and surface property. However, the investigation of oxygen vacancies in nonmetal oxides and…
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Keywords:
boron nitride;
propane;
oxygen vacancies;
propene ... See more keywords
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Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.09.033
Abstract: Abstract Investigation of reaction mechanisms by identifying the intermediates released into the gas phase is most effective at low conversion of reactants, ideally approaching zero. However, conversions below 0.5–1% are rarely used, due to the…
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Keywords:
mechanism;
conversion;
investigation;
ultralow conversion ... See more keywords
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Published in 2021 at "Materials Research Bulletin"
DOI: 10.1016/j.materresbull.2020.111089
Abstract: Abstract We have performed the synthesis of TiO2-MWCNT composites focusing on the distribution of the photoactive phase on the carbon active sites existing in the MWCNTs, and its effect on the properties of the composites…
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Keywords:
dispersion;
mwcnt;
propene;
tio2 mwcnt ... See more keywords
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Published in 2020 at "Sustainable Chemistry and Pharmacy"
DOI: 10.1016/j.scp.2020.100273
Abstract: Abstract Deoxydehydration (DODH) reaction on 1,2-propanediol (1,2-PD) catalyzed by rhenium, conducted in 2,4-dimethyl-3-pentanol (DMP) or in neat 1,2-PD, was carried out. The experimental apparatus was planned to recover separately all the reaction products: in one…
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Keywords:
new green;
deoxydehydration;
reaction;
green route ... See more keywords
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Published in 2018 at "Surface Science"
DOI: 10.1016/j.susc.2018.06.007
Abstract: Abstract Inelastic electron tunneling through single molecules located in the tunnel junction between a surface and the tip of a scanning tunneling microscope may cause molecular surface dynamics. Vibrations excited by inelastically tunneling electrons may…
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Keywords:
molecule;
tunneling single;
electron tunneling;
electron ... See more keywords
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Published in 2018 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.8b00377
Abstract: Hierarchical zeolite ZSM-58 was synthesized via a bottom-up synthesis method using varying amounts of carbon nanotubes (CNTs) as mesopore-generating template. Resulting ZSM-58 samples were analyzed by X-ray powder diffraction, scanning electron microscopy and physisorption experiments…
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Keywords:
adsorption;
zeolite zsm;
propane;
hierarchical zeolite ... See more keywords
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Published in 2018 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.8b03233
Abstract: A continuous hydrogen peroxide propene oxide (HPPO) lab-scale pilot plant was designed and tested for the production of propene oxide via HPPO process. The plant was equipped with a continuous stirred tank reactor, able to…
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Keywords:
propene oxide;
plant;
hydrogen peroxide;
process ... See more keywords
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Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c06295
Abstract: The selective oxidation of propene to propene oxide (PO) is an industrially relevant and still challenging reaction that requires the design of highly specific catalysts able to improve simultaneou...
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Keywords:
role cluster;
epoxidation propene;
cluster morphology;
crucial role ... See more keywords
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Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c04793
Abstract: In this work, we reported the preparation of composites based on titania (TiO2) and Zeolite Socony Mobil-5 (ZSM-5) nanozeolite, following two approaches (i.e., incorporating the presynthesized zeolite in the synthesis medium of TiO2 and incorporating…
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Keywords:
tio2;
phase;
microscopy;
spectroscopy ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c10248
Abstract: Low-temperature removal of noxious environmental emissions plays a critical role in minimizing the harmful effects of hydrocarbon fuels. Emission-control catalysts typically consist of large quantities of rare, noble metals (e.g., platinum and palladium), which are…
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Keywords:
low temperature;
colloidal platinum;
propene;
platinum ... See more keywords
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Published in 2021 at "Materials"
DOI: 10.3390/ma14174814
Abstract: Palladium-modified Co-ZnAland Cu-ZnAl materials were used and found active for the catalytic oxidation of propene and propane. According to the results obtained by XRD, TPR and XPS, the zinc aluminate-supported phases are oxide phases, Co3O4,…
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Keywords:
znal znal;
oxidation;
activity;
effect ... See more keywords