Articles with "properties bridged" as a keyword



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Computational study of ground-state properties of μ2 -bridged group 14 porphyrinic sandwich complexes.

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Published in 2022 at "Journal of computational chemistry"

DOI: 10.1002/jcc.26870

Abstract: The structural properties of μ2 -bridged porphyrinic double-decker complexes are investigated and the influence of various ligands, metals, substituents, and bridging atoms on the dominant structural motif is elucidated. A variety of quantum chemical methods… read more here.

Keywords: bridged group; ground state; computational study; properties bridged ... See more keywords
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Tuning of magnetic properties of the 2D CN-bridged NiII-NbIV framework by incorporation of guest cations of alkali and alkaline earth metals.

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Published in 2021 at "Dalton transactions"

DOI: 10.1039/d1dt00367d

Abstract: The reaction between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [Nb(CN)8]4- in concentrated water solutions of different s-block metal salts leads to the formation of 2-dimensional honeycomb-like coordination networks of the formula Mx[Ni(cyclam)]3[Nb(CN)8]2·nH2O (x = 2: M… read more here.

Keywords: bridged niii; tuning magnetic; magnetic properties; guest cations ... See more keywords