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Published in 2022 at "Journal of computational chemistry"
DOI: 10.1002/jcc.26870
Abstract: The structural properties of μ2 -bridged porphyrinic double-decker complexes are investigated and the influence of various ligands, metals, substituents, and bridging atoms on the dominant structural motif is elucidated. A variety of quantum chemical methods…
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Keywords:
bridged group;
ground state;
computational study;
properties bridged ... See more keywords
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1
Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00367d
Abstract: The reaction between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [Nb(CN)8]4- in concentrated water solutions of different s-block metal salts leads to the formation of 2-dimensional honeycomb-like coordination networks of the formula Mx[Ni(cyclam)]3[Nb(CN)8]2·nH2O (x = 2: M…
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Keywords:
bridged niii;
tuning magnetic;
magnetic properties;
guest cations ... See more keywords