Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe 2 (CO) 4 (κ 2 ‐P Ph 2 N R 2 )( µ ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H 2 ases
Sign Up to like & getrecommendations! Published in 2020 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202000824
Abstract: A series of dithiolate carbonyl diiron complexes with cyclic azadiphosphine, related to the active site of [FeFe]‐hydrogenases, has been prepared. Several combinations of diphosphines and dithiolate bridges have been examined in order to obtain information… read more here.
Keywords: synthesis characterization; properties complexes; characterization electrochemical; reductive properties ... See more keywords
Luminescent properties of Zn complexes based on tetradentate N2O2-donor pyrazolone schiff bases
Sign Up to like & getrecommendations! Published in 2020 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2020.108626
Abstract: Abstract A nine new Zn(II) complex were synthesized based on a new Salen-type tetradentate N2O2 ligands derived from 1-phenyl-3-methyl-4-formyl-5-pyrazolone. Complexes have been characterized by single-crystal X-ray diffraction, ESI-mass spectroscopy, elemental analysis, IR spectroscopy and thermal… read more here.
Keywords: pyrazolone; luminescent properties; tetradentate n2o2; complexes based ... See more keywords
Synthesis, crystal structures and electrochemical properties of Co(II) and Mn(II) complexes with asymmetric bulky BIAN ligands
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DOI: 10.1016/j.poly.2018.03.034
Abstract: Abstract Series of newly designed Co(II) and Mn(II) complexes supported by sterically encumbered asymmetric bis(imino)acenaphthene (BIAN) ligands were synthesized through the reaction of metal dichlorides with the corresponding ligands. The metal complexes were characterized by… read more here.
Keywords: electrochemical properties; bian ligands; structures electrochemical; crystal structures ... See more keywords
Electronic properties of the S = 5/2 Mn(II) complexes [Mn{PhC(O)NP(O)PPh2}(N,N)(NO3)], (N,N) = phenanthroline, neocuproine, 2,2′-bipyridine
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DOI: 10.1016/j.poly.2021.115374
Abstract: Abstract The synthesis, as well as the structural and electronic properties of the [Mn(O,O)(N,N)(NO3)] complexes, (O,O) = {PhC(O)NP(O)PPh2}−, (N,N) = phenanthroline (1), neocuproine (2) and 2,2′-bipyridine (3) is reported. The three complexes were structurally characterized by X-ray crystallography, and… read more here.
Keywords: phenanthroline neocuproine; electronic properties; properties complexes; complexes phc ... See more keywords
Dimensional regulation of the aggregation-induced emission properties for complexes
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DOI: 10.1039/d3qi00443k
Abstract: Two similar ligands (tpemc and tpedc) with few coordination sites were used to design and construct a series of Eu-complexes with three different dimensions in this work. Complexes 1–3 showed an incremental AIE phenomenon. read more here.
Keywords: properties complexes; dimensional regulation; induced emission; aggregation induced ... See more keywords
Modulation of the Cytotoxic Properties of Pd(II) Complexes Based on Functionalized Carboxamides Featuring Labile Phosphoryl Coordination Sites
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DOI: 10.3390/pharmaceutics15041088
Abstract: Platinum-based drugs are commonly recognized as a keystone in modern cancer chemotherapy. However, intrinsic and acquired resistance as well as serious side effects often caused by the traditional Pt(II) anticancer agents prompt a continuous search… read more here.
Keywords: modulation cytotoxic; cytotoxic properties; functionalized carboxamides; cytotoxic ... See more keywords