Synthesis, characterization and electronic properties of an endohedral plumbaspherene [Au@Pb12]3−
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry frontiers"
DOI: 10.1039/c7qi00209b
Abstract: We report the synthesis, characterization and DFT studies of a transition-metal-encapsulated superatom compound, [K(2,2,2-crypt)]3[Au@Pb12]·2py, which adopts a distorted symmetry instead of the icosahedral structure due to the second-order Jahn–Teller effect. DFT computations revealed its chemical… read more here.
Keywords: endohedral plumbaspherene; characterization electronic; electronic properties; properties endohedral ... See more keywords