Cyclometalated Platinum(II) Complexes in a Cis-N,N Configuration: Photophysical Properties and Isomerization to Trans Isomers.
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DOI: 10.1021/acs.inorgchem.1c03295
Abstract: Synthesis, isomerization, and photophysical properties of novel cis-N,N-cyclometalated complexes [Pt(C∧N)(l-Phe)] (C∧N = benzoquinolinate (1), phenylpyridinate (2), 2-(p-tolyl)pyridinate (3), and 1-phenylpyrazolate (4); l-Phe- = l-phenylalaninate) are reported herein. In solution, the cis forms of the complexes… read more here.
Keywords: properties isomerization; photophysical properties; cis; trans isomers ... See more keywords