Photophysical Properties of Pt(II) Polypyridines with Five- versus Six-Membered Chelate Rings: Trade-Offs in Angle Strain.
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DOI: 10.1021/acs.inorgchem.8b00636
Abstract: This report describes the synthesis and characterization of a series of eight [Pt(NNN)X]+ complexes where the tridentate NNN ligand is (2,2'-bipyrid-6-yl)(pyrid-2-yl)sulfide (btp) or methyl(2,2'-bipyrid-6-yl)(pyrid-2-yl)amine (bmap) and X is OMe, Cl, phenylethynyl (C2Ph), or cyclohexylethynyl (C2Cy).… read more here.
Keywords: angle; six membered; angle strain; properties polypyridines ... See more keywords