Kinetics and mechanism of ethylene and propylene polymerizations catalyzed with ansa-zirconocene activated by borate/TIBA
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DOI: 10.1016/j.jorganchem.2020.121366
Abstract: Abstract Ethylene and propylene polymerizations catalyzed with two ansa-zirconocenes (rac-Me2Si(2-Me-4-Ph-Ind)2ZrCl2 (M-I) and rac-Et(Ind)2ZrCl2 (Mt-II)) activated by (Ph3C)B(C6F5)4/triisobutylaluminum were respectively conducted under the same conditions for different duration ranging from 0.5 to 30 min, and quenched with… read more here.
Keywords: propylene polymerizations; ethylene propylene; polymerization; time ... See more keywords