Unexpected Formation and Characterization of 1-(Alkylsulfonyl)alkyl Alkanethiosulfonates via Elimination of Alkanesulfinyl Chlorides.
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DOI: 10.1021/acs.jafc.5c08578
Abstract: During the preparation of propanethial S-oxide via the elimination reaction of propanesulfinyl chloride, a cepaene-like oxide product, 1-(propylsulfonyl)propyl propanethiosulfonate, was unexpectedly obtained. The structure of this product was unambiguously confirmed by HRMS, 1H NMR, 13C… read more here.
Keywords: via elimination; unexpected formation; propylsulfonyl propyl; elimination ... See more keywords